Citation: Li Pengshuai, Wu Yun, Bai Chaolumen, Bao Yongsheng. Insight into Catalytic Properties of Supported Palladium Nanoparticles Catalyzed ortho-Directed Sulfonylation[J]. Chinese Journal of Organic Chemistry, ;2020, 40(7): 1991-1998. doi: 10.6023/cjoc202003020 shu

Insight into Catalytic Properties of Supported Palladium Nanoparticles Catalyzed ortho-Directed Sulfonylation

Inner Mongolia Key Laboratory of Green Catalysis, College of Chemistry and Environmental Science, Inner Mongolia Normal University, Hohhot 010022

Corresponding author: Bao Yongsheng, sbbys197812@163.com
Received Date: 8 March 2020
Revised Date: 11 April 2020

Fund Project: and the Program for Young Talents of Science and Technology in Universities of Inner Mongolia autonomous Region NJYT-17-a22National Natural Science Foundation of China (No. 21861030), and the Program for Young Talents of Science and Technology in Universities of Inner Mongolia autonomous Region (No. NJYT-17-a22)National Natural Science Foundation of China 21861030

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Catalyzed by supported palladium nanoparticles, an ortho-directed sulfonylation reaction between 2-phenylpyri-dine and arylsulfonyl chlorides has been developed. The full oxidation-state change of palladium was detected in the X-ray photoelectron spectroscopy (XPS) analysis of the supported palladium nanoparticles catalyst before and after reaction, which confirmed that Pd-catalyzed ortho-directed sulfonylation reaction was performed via a Pd^Ⅱ/IV catalytic cycle instead of Pd^0/Ⅱ. The hot filtration test and other tests of catalysts further confirmed the hypothesis. This report afforded the most straightforward approach to confirm the variation of valence of palladium in ortho-directed sulfonylation reaction.
- C-H functionalization,
- X-ray photoelectron spectroscopy (XPS) analysis,
- palladium nanoparticles catalyst,
- sulfonylation
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