Citation: Zong Lingbo, Chen Jianbin, Ren Xinyi, Zhang Guoying, Jia Xiaofei. Progress in Application of Organic Polymers Supported Rhodium Catalysts in Hydroformylation[J]. Chinese Journal of Organic Chemistry, ;2020, 40(8): 2308-2321. doi: 10.6023/cjoc202003006 shu

Progress in Application of Organic Polymers Supported Rhodium Catalysts in Hydroformylation

a.
Shandong Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao, Shandong 266042
b.
Shandong Provincial Key Laboratory of Molecular Engineering, School of Chemistry and Chemical Engineering, Qilu University of Technology, Jinan 250353
c.
Shanghai Key Laboratory of Green Chemistry and Chemical Process, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241

Corresponding author: Jia Xiaofei, jiaxiaofei139@163.com
Received Date: 3 March 2020
Revised Date: 1 May 2020
Available Online: 19 May 2020
Fund Project: Open Fund of the Department of Chemistry, Qingdao University of Science and Technology QUSTHX202010Open Fund of the Department of Chemistry, Qingdao University of Science and Technology QUSTHX201932National Natural Science Foundation of China 21703116National Natural Science Foundation of China 51702180Project supported by the National Natural Science Foundation of China (Nos. 21703116, 51702180) and the Open Fund of the Department of Chemistry, Qingdao University of Science and Technology (Nos. QUSTHX201932, QUSTHX202010)

Figures(27)

Hydroformylation is considered one of the most important homogenously catalyzed processes in dustry. Hydroformylation has been widely used in the production of aldehydes, and aldehydes can also be further converted into high value-added alcohols, acids and other derivatives. Compared with the homogeneous reaction, the heterogeneous catalysts present significant advantages in terms of recyclability, separation of catalysts and products and so on. In recent years, organic polymer-supported rhodium catalysts have shown excellent catalytic activity, high selectivity, and good recycleability in heterogeneous hydroformylation, and have attracted widespread attention. The research progress of the application of organic polymer supported catalysts in hydroformylation is summarized, including synthesis, material characteristics and application of supported catalysts. Finally, the prospect of the reaction is discussed.
- rhodium,
- hydroformylation,
- organic polymers,
- heterogeneous catalysts
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