Citation: Yao Ming, Zhang Jingjing, Yang Sen, Xiong Hangxing. γ-Aluminum Oxide-Mediated Iodination of Terminal Alkynes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(7): 2153-2158. doi: 10.6023/cjoc202002014 shu

γ-Aluminum Oxide-Mediated Iodination of Terminal Alkynes

Yao Ming ^a,, ,
Zhang Jingjing ^a,b ,
Yang Sen ^a ,
Xiong Hangxing ^a,b,,

a.
College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jingmen, Hubei 448000
b.
School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430205

Corresponding author: Yao Ming, yaomingcep@jcut.edu.cn Xiong Hangxing, 731990153@qq.com
Received Date: 13 February 2020
Revised Date: 27 March 2020
Available Online: 13 April 2020
Fund Project: Project supported by the Science Technology Foundation for Creative Research Group of Hubei Department of Education (No. T201719)the Science Technology Foundation for Creative Research Group of Hubei Department of Education T201719

Figures(2)

A simple two-step, one-pot synthesis of 1, 2, 2-triiodovinyl derivatives from terminal alkynes using N-iodosuc-cinimide and iodine as precursors, activated with γ-aluminum oxide is developed. This approach resulted in moderate to excellent yields, good functional group tolerance and utilization of an inexpensive catalyst.
- terminal alkyne,
- iodination,
- aluminum oxide,
- 1, 2, 2-triiodovinyl derivative,
- one-pot process
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