Citation: Xu Xinming, Yang Hanlin, Li Wenzhong. Transition Metal-Free Direct C-H Bond Sulfenylation of Alkenes and Arenes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(7): 1912-1925. doi: 10.6023/cjoc201912044 shu

Transition Metal-Free Direct C-H Bond Sulfenylation of Alkenes and Arenes

a.
College of Chemistry and Chemical Engineering, Yantai University, Yantai, Shandong 264005

Corresponding author: Xu Xinming, xin_mingxu@163.com
Received Date: 31 December 2019
Revised Date: 16 March 2020
Available Online: 9 April 2020
Fund Project: the National Natural Science Foundation of China 21901220the Young Scholars Research Fund of Yantai University HY19B06Project supported by the National Natural Science Foundation of China (No. 21901220), and the Young Scholars Research Fund of Yantai University (No. HY19B06)

Figures(33)

Aryl and vinyl sulfides have attracted much attention from medical and organic chemists because they are prevalent in natural or bioactive molecules and other potential functional organic materials. Therefore, considerable efforts have been made for the construction of aryl and vinyl sulfides, among them transition metal-free direct C-H bond sulfenylation has developed rapidly and became an efficient and eco-friendly synthetic protocol. In recent years, many excellent research achievements were presented and a range of sulfenylated alkenes and arenes were synthesized using this strategy. The recent five-year progress in direct sulfenylation of C-H bond on alkenes and arenes under transition metal-free conditions is reviewed and the corresponding reaction mechanisms are discussed.
- sulfenylation,
- transition metal-free condition,
- C-H bond,
- reaction mechanism
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沈阳化工大学材料科学与工程学院沈阳 110142