Citation: Hu Zhixiong, Sun Dongdong, Han Xie, Liu Simin. Molecular Recognition of Cucurbit[10]uril toward Planar d⁸ and d¹⁰ Transition Metal Complexes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(5): 1361-1366. doi: 10.6023/cjoc201912014 shu

Molecular Recognition of Cucurbit[10]uril toward Planar d⁸ and d¹⁰ Transition Metal Complexes

State Key Laboratory of Refractories and Metallurgy, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081

Corresponding author: Liu Simin, liusimin@wust.edu.cn
Received Date: 10 December 2019
Revised Date: 11 January 2020
Available Online: 21 January 2020
Fund Project: the National Natural Science Foundation of China 21472143Project supported by the National Natural Science Foundation of China (Nos. 21871216, 21901194, 21472143)the National Natural Science Foundation of China 21901194the National Natural Science Foundation of China 21871216

Figures(13)

Due to the coordination-unsaturation feature of d⁸ and d¹⁰ transition metals, their unique electronic structures and easy formation of metal-metal bonds make them exhibit special photophysical and photochemical properties. The optical properties of luminescent molecules can be regulated through host-guest interactions. In order to further explore the effect of host-guest interaction on the optical properties of d⁸ and d¹⁰ transition metal complexes, the member with the largest cavity in the macrocyclic family of cucurbit[n]uril (CB[n], n=5~8, 10)-CB[10] was selected as host. The changes in photophysical properties of such water-soluble planar transition metal complexes after entering the host cavity were studied by means of UV/Vis, fluorescence, ¹H NMR and mass spectra. The results show that the cavity of CB[10] can accommodate multiple Pt(Ⅱ) complex molecules. By enhancing the π-π interaction between guest molecules in the cavity of CB[10], the distance between metal atoms was shortened, leading the formation of metal-metal interactions in the water phase. Encapsulation of Ir(Ⅲ)complex in CB[10] causes the formation of excimer. In addition, strong metal-metal interactions between Rh(Ⅰ) complex molecules were weakened after the guest went into CB[10], which should be attributed to the formation of 1:1 host-guest complex. The introduction of host-guest chemistry in regulating photophysical properties of d⁸ and d¹⁰ metal complexes would further expand the application of transition metal complexes in a wider range of fields.
- transition metal complex,
- host-guest interaction,
- cucurbit[n]uril,
- inclusion complex,
- metal-metal interaction
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Molecular Recognition of Cucurbit[10]uril toward Planar d8 and d10 Transition Metal Complexes

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Molecular Recognition of Cucurbit[10]uril toward Planar d⁸ and d¹⁰ Transition Metal Complexes