Citation: Xiao Tangxin, Zhou Ling, Wei Xiaoyan, Li Zhengyi, Sun Xiaoqiang. Supramolecular Copolymers Driven by Quadruple Hydrogen Bonding and Host-Guest Interactions[J]. Chinese Journal of Organic Chemistry, ;2020, 40(4): 944-949. doi: 10.6023/cjoc201911014 shu

Supramolecular Copolymers Driven by Quadruple Hydrogen Bonding and Host-Guest Interactions

School of Petrochemical Engineering, Changzhou University, Changzhou, Jiangsu 213164

Corresponding author: Xiao Tangxin, xiaotangxin@cczu.edu.cn Sun Xiaoqiang, xqsun@cczu.edu.cn
Received Date: 7 November 2019
Revised Date: 30 November 2019
Available Online: 19 December 2019
Fund Project: the National Natural Science Foundation of China 21702020the National Natural Science Foundation of China 21572026Project supported by the National Natural Science Foundation of China (Nos. 21702020, 21572026)

Figures(5)

A heteroditopic monomer (H) comprised of ureidopyrimidinone (UPy) group and benzo-21-crown-7 motif and a homoditopic monomer (G) containing two dialkylammonium salt units have been successfully prepared. The functional groups both in H and G are linked together by a short spacer. Through quadruple hydrogen bonds, H can self-assemble into dimers, which are capable of complexing with G via host-guest interaction to form linear supramolecular copolymers. The supramolecular copolymers were fully characterized by various techniques, such as concentration-dependent ¹H NMR, viscosity measurements, and scanning electron microscope (SEM). The results will inspire the orthogonal construction of supramolecular polymers for smart materials in more fields.
- supramolecular chemistry,
- quadruple hydrogen bonds,
- self-assembly,
- supramolecular polymer,
- crown ethers,
- macrocycles,
- host-guest interaction
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