Citation: Tian Wanfa, Li Na, Peng Zihe, Feng Lihua, Mai Xi, He Yongqin. Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C—H Functionalization of Arenes[J]. Chinese Journal of Organic Chemistry, ;2020, 40(3): 625-644. doi: 10.6023/cjoc201909015 shu

Recent Advances in Ligand-Promoted Transition-Metal-Catalyzed Remote meta-C—H Functionalization of Arenes

Tian Wanfa ^b ,
Li Na ^a ,
Peng Zihe ^c ,
Feng Lihua ^a ,
Mai Xi ^a ,
He Yongqin ^a,,

a.
School of Pharmaceutical Science, Nanchang University, Nanchang 330000
b.
Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330000
c.
Fuzhou Medical College, Nanchang University, Fuzhou, Jiangxi 344000

Corresponding author: He Yongqin, heyq12@lzu.edu.cn
Received Date: 9 September 2019
Revised Date: 27 November 2019
Available Online: 19 December 2019
Fund Project: Project supported by the National Natural Science Foundation of China (No. 81860610) and the Young Teachers Training Foundation of Nanchang University(No. 4209-16100009-PY201810)the National Natural Science Foundation of China 81860610the Young Teachers Training Foundation of Nanchang University 4209-16100009-PY201810

Figures(50)

Ligands can regulate both the steric and electronic effects of the catalytic center in transition-metal-catalyzed C-H activation reactions, leading to the site-selective C-H functionalization of arenes. In recent years, ligand-promoted remote C-H functionalization of arenes has developed rapidly. The recent progress on ligand-promoted transition-metal-catalyzed remote meta-selective C-H bond functionalization of arenes is summarized, and the limitations of the research field and prospects for future development are presented.
- transition metal catalysis,
- remote meta-C—H bond,
- functionalization,
- ligand promotion
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