Citation: Wang Jiao, Yao Hong, Zhou Qi, Kan Xiaotong, Fan Yanqing, Guan Xiaowen, Zhang Youming, Lin Qi, Wei Taibao. Molecule-Responsive Supramolecular Hydrogel Constructed from Pillar[5]arene Based on Host-Guest System[J]. Chinese Journal of Organic Chemistry, ;2020, 40(1): 175-180. doi: 10.6023/cjoc201907042 shu

Molecule-Responsive Supramolecular Hydrogel Constructed from Pillar[5]arene Based on Host-Guest System

Key Laboratory of Eco-environmental Polymer Materials of Gansu Province, Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: Yao Hong, yhxbz@126.com Wei Taibao, weitaibao@126.com
Received Date: 27 July 2019
Revised Date: 7 September 2019
Available Online: 18 January 2019
Fund Project: the National Natural Science Foundation of China 21574104the National Natural Science Foundation of China 21662031Project supported by the National Natural Science Foundation of China (Nos. 21662031, 21661028, 21574104)the National Natural Science Foundation of China 21661028

Figures(6)

The host-guest interaction was qualified as an ideal drive force to form stable inclusion complexes with macrocyclic host molecules in aqueous solution. Herein, a multi-responsive supramolecular hydrogel was constructed based on a functionalized benzimidazole derivative guest (M) with soluble pillar[5]arene as a host group. The mechanism of hydrogel formation was explored by the ¹H NMR, 2D NOESY and scanning electron microscope (SEM) in depth study. Interestingly, host-guest inclusion, the ordered "exo-wall" π-π interaction and hierarchical stacking of pillar[5]arene was indispensable to obtain the supramolecular hydrogel, which endowed the gel system with response to temperature change/chemical stimuli. Upon addition of competitive guests adiponitrile (ADN)/paraquat (PQ), pillar[5]arene-based hydrogel could be converted into sol. Herein, the organic molecules could be selectively recognized by the hydrogel.
- supramolecular hydrogel,
- soluble pillar[5]arene,
- competitive inclusion,
- molecular recognition,
- self assembly
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