Citation: Zhong Wenwu, Tang Qian, Yang Zongfa, Zeng Xue, Gan Linling, Lan Zuoping, Yang Yuanjuan. Decarboxylative Oxyphosphorylation of Alkynyl Carboxylic Acids with H-Phosphonates Catalyzed by Cu-Cu₂O/GO-NH₂[J]. Chinese Journal of Organic Chemistry, ;2019, 39(12): 3467-3474. doi: 10.6023/cjoc201907010 shu

Decarboxylative Oxyphosphorylation of Alkynyl Carboxylic Acids with H-Phosphonates Catalyzed by Cu-Cu₂O/GO-NH₂

Zhong Wenwu ^a,b,c ,
Tang Qian ^a,b,c ,
Yang Zongfa ^a,b ,
Zeng Xue ^a,b ,
Gan Linling ^a,b ,
Lan Zuoping ^a,b,, ,
Yang Yuanjuan ^a,b,c,,

a.
Chongqing Medical and Pharmaceutical College, Chongqing 401331
b.
Chongqing Engineering Technology Research Center of Pharmaceutical Sciences, Chongqing 401331
c.
National Second-level Scientific Research Laboratory of the Quality Testing of Traditional Chinese Medicine, Chongqing 401331

Corresponding author: Lan Zuoping, lanzuop@126.com Yang Yuanjuan, Yang_1889@sina.com
Received Date: 4 July 2019
Revised Date: 13 August 2019
Available Online: 30 December 2019
Fund Project: the Scientific Research Project of Chongqing Medical and Pharmaceutical College ygz2018102the Medical Scientific Research Project of Chongqing Municipal Health and Family Planning Commission 20142116the Medical Scientific Research Project of Chongqing Municipal Health and Family Planning Commission 2012-1-093the Chinese Medicine Science and Technology Project of Chongqing Municipal Health and Family Planning Commission ZY201402158the Scientific and Technological Research Project of Chongqing Municipal Education Commission KJ1726394Project supported by the Scientific Research Project of Chongqing Medical and Pharmaceutical College (Nos. ygz2018303, ygz2018102), the Medical Scientific Research Project of Chongqing Municipal Health and Family Planning Commission (Nos. 2012-1-093, 20142116), the Chinese Medicine Science and Technology Project of Chongqing Municipal Health and Family Planning Commission (No. ZY201402158), and the Scientific and Technological Research Project of Chongqing Municipal Education Commission (No. KJ1726394)the Scientific Research Project of Chongqing Medical and Pharmaceutical College ygz2018303

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A graphene based hybrid with copper nanoparticles (Cu-Cu₂O/GO-NH₂) as a heterogeneous catalyst for the preparation of β-ketophosphonates was investigated. Compared with traditional homogeneous catalysis, Cu-Cu₂O/GO-NH₂ catalyst can be recovered from the reaction system. The present methodology provides a facile and efficient approach to access a wide range of β-ketophosphonates in good yields. This reaction can be conducted under base-free conditions without any external co-catalysts, which provides an alternative strategy for the synthesis of β-ketophosphonates.
- Cu nanoparticles,
- graphene,
- oxyphosphorylation,
- heterogeneous catalysis,
- β-ketophosphonates
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Decarboxylative Oxyphosphorylation of Alkynyl Carboxylic Acids with H-Phosphonates Catalyzed by Cu-Cu2O/GO-NH2

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通讯作者: 陈斌, bchen63@163.com

Decarboxylative Oxyphosphorylation of Alkynyl Carboxylic Acids with H-Phosphonates Catalyzed by Cu-Cu₂O/GO-NH₂