Citation: Kong Yaolei, Xu Wenxiu, Ye Feixia, Weng Jianquan. Recent Advances in Visible-Light-Induced Cross Dehydrogenation Coupling Reaction under Transition Metal-Free Conditions[J]. Chinese Journal of Organic Chemistry, ;2019, 39(11): 3065-3083. doi: 10.6023/cjoc201905016 shu

Recent Advances in Visible-Light-Induced Cross Dehydrogenation Coupling Reaction under Transition Metal-Free Conditions

College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014

Corresponding author: Weng Jianquan, jqweng@zjut.edu.cn
Received Date: 9 May 2019
Revised Date: 5 June 2019
Available Online: 9 November 2019
Fund Project: Project supported by the Natural Science Foundation of Zhejiang Province (No. LY17C140003)the Natural Science Foundation of Zhejiang Province LY17C140003

Figures(20)

The cross dehydrogenation coupling reaction realizes direct coupling of two different X-H bonds to form a new chemical bond, thus featuring excellent step and atom economy. The traditional cross dehydrogenation coupling reaction was usually catalyzed by transition metal, which had the problems of expensive catalyst and serious pollution. Visible light-induced electron transfer is also an effective way to realize direct functionalization of X-H bonds. Visible-light-induced cross dehydrogenation coupling reaction under transition metal-free conditions is widely concerned due to the advantages of cleanliness, safety as well as high step and atom economy. Classified by the type of bonding, the research progress of these reactions is reviewed, and their future outlook is also discussed.
- cross dehydrogenation coupling,
- visible-light-induced,
- transition metal-free,
- functionalization
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沈阳化工大学材料科学与工程学院沈阳 110142