Citation: Mao Pu, Zhu Junliang, Yuan Jinwei, Yang Liangru, Xiao Yongmei, Zhang Changsen. Recent Advances on the Catalytic Functionalization of Quinoxalin- 2(1H)-ones via C-H Bond Activation[J]. Chinese Journal of Organic Chemistry, ;2019, 39(6): 1529-1547. doi: 10.6023/cjoc201904025 shu

Recent Advances on the Catalytic Functionalization of Quinoxalin- 2(1H)-ones via C-H Bond Activation

a.
Academician Workstation for Natural Medicinal Chemistry of Henan Province, School of Chemistry & Chemical Engineering, Henan Univeristy of Technology, Zhengzhou 450001
b.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001

Corresponding author: Yuan Jinwei, yuanjinweigs@126.com
Received Date: 10 April 2019
Revised Date: 24 April 2019
Available Online: 6 June 2019
Fund Project: the Project of Youth Backbone Teachers of Henan University of Technology 2016003the Department of Henan Province Natural Science and Technology Foundation 172102210225the Program for Innovative Research Team from Zhengzhou 131PCXTD605Project supported by the Department of Henan Province Natural Science and Technology Foundation (Nos.172102210225 and 182102310675), the Natural Science Foundation in Henan Province Department of Education (No.17A150005), the Program for Innovative Research Team from Zhengzhou (No. 131PCXTD605), and the Project of Youth Backbone Teachers of Henan University of Technology (No.2016003)the Department of Henan Province Natural Science and Technology Foundation 182102310675the Natural Science Foundation in Henan Province Department of Education 17A150005

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Quinoxalin-2(1H)-ones are very important N-heterocyclic moieties found in natural products and pharmaceuticals, and exhibit an amazingly wide spectrum of biological properties. Numerous efforts have been devoted to the development of efficient approaches for the C-H bond activation and functionalization of quinoxalin-2(1H)-ones in recent years, including alkylation, benzylation, acylation, arylation, amination, amidation, phosphonation, and fluoroalkylation. The recent advances in this area are summarized and their reaction mechanisms are discussed.
- quinoxalin-2(1H)-one,
- C-H bond activation,
- functionalization,
- transition-metal catalyst
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