Citation: Gu Yingchun, Huang You. Tributylphosphine Catalyzed Cross Rauhut-Currier Reaction of Chalcones and Acrylates[J]. Chinese Journal of Organic Chemistry, ;2019, 39(8): 2251-2256. doi: 10.6023/cjoc201904017 shu

Tributylphosphine Catalyzed Cross Rauhut-Currier Reaction of Chalcones and Acrylates

Gu Yingchun ^a,b ,
Huang You ^a,,

a.
State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071
b.
School of Science, Tianjin Chengjian University, Tianjin 300384

Corresponding author: Huang You, hyou@nankai.edu.cn
Received Date: 8 April 2019
Revised Date: 4 May 2019
Available Online: 15 August 2019
Fund Project: the National Natural Science Foundation of China 21472097the National Natural Science Foundation of China 21672109the National Natural Science Foundation of China 21871148the Natural Science Foundation of Tianjin City 15JCYBJC20000Project supported by the National Natural Science Foundation of China (Nos. 21672109, 21871148, 21472097) and the Natural Science Foundation of Tianjin City (No. 15JCYBJC20000)

Figures(1)

Rauhut-Currier (RC) reaction is an effective atom-economic method to construct C-C bond. However, the application of this reaction is limited by the lack of selectivity. Herein, an efficient intermolecular cross Rauhut-Currier reaction between chalcones and acrylates in the presence of the tributylphosphine catalyst was developed, the reactions were carried out in mild conditions, and performed well with a series of substrates, delivering the desired products with acceptable to good yields.
- tributylphosphine,
- catalysis,
- Rauhut-Currier reaction,
- chalcone,
- acrylate
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