Citation: Yin Qing, Yu Xiaoqiang, Bao Ming. A Novel Method for the Synthesis Triarylphosphines under Transition-Metal-Free Conditions[J]. Chinese Journal of Organic Chemistry, ;2019, 39(10): 2930-2935. doi: 10.6023/cjoc201904006 shu

A Novel Method for the Synthesis Triarylphosphines under Transition-Metal-Free Conditions

State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024

Corresponding author: Yu Xiaoqiang, yuxiaoqiang@dlut.edu.cn
Received Date: 2 April 2019
Revised Date: 26 April 2019
Available Online: 21 October 2019
Fund Project: the National Natural Science Foundation of China Nos. 21572028, 21573032Project supported by the National Natural Science Foundation of China (Nos. 21572028, 21573032)the National Natural Science Foundation of China 21573032

Figures(2)

Triarylphosphines play an important role in pharmaceutical synthesis and transition-meal-catalyzed reactions. In this paper, a novel method for the synthesis of triarylphosphines via base-promoted C(sp²)-P cross-coupling reactions of alkyldiphenylphosphines with aryl halides is described. The transition-metal-free reaction condition, readily available starting materials and experimental simplicity are the features of the novel method.
- transition metal-free,
- alkyldiphenylphosphines,
- aryl halides,
- triarylphosphines
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