Citation: Zhu Wenbo, Zhu Wei, Ding Jindong, Ma Xiaoqiang, Yao Hong, Zhang Youming, Lin Qi, Wei Taibao. A Novel Fluorescent Sensor Based on Aryl-furfural Functionalized Barbituric Acid for Recognition and Separation of Hg²⁺/Fe³⁺[J]. Chinese Journal of Organic Chemistry, ;2019, 39(10): 2829-2834. doi: 10.6023/cjoc201903053 shu

A Novel Fluorescent Sensor Based on Aryl-furfural Functionalized Barbituric Acid for Recognition and Separation of Hg²⁺/Fe³⁺

Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070

Corresponding author: Lin Qi, weitaibao@126.com Wei Taibao, linqi2004@126.com
Received Date: 24 March 2019
Revised Date: 13 May 2019
Available Online: 6 October 2019
Fund Project: the National Natural Science Foundation of China 21661028the National Natural Science Foundation of China 21662031the National Natural Science Foundation of China 21262032Project supported by the National Natural Science Foundation of China (Nos. 21662031, 21661028, 21574104, 21262032)the National Natural Science Foundation of China 21574104

Figures(7)

A novel fluorescent sensor based on 5-(3-nitrophenyl)-furan-2-carbaldehyde functionalized barbituric acid derivative (QS) was successfully synthesized. QS was characterized by ¹H NMR, ¹³C NMR and MS. The maximum fluorescence emission wavelength of QS in dimethyl sulfoxide (DMSO) solution was determined to be 498 nm and green fluorescence was emitted under 365 nm ultraviolet lamp. QS showed different fluorescence identification ability for aqueous solution of Hg²⁺ and Fe³⁺. Hg²⁺ can enhance the fluorescence of probe QS to orange, and Fe³⁺ quenches its fluorescence, thus realizing real-time detection. The limits of detection of QS for Hg²⁺ and Fe³⁺ are 3.25×10^-8 and 4.0×10^-8 mol· L^-1, respectively. The fluorescence measurements and MS studies suggest that the binding stoichiometry ratios of QS with Hg²⁺ and Fe³⁺ are recognized as 1:1, respectively. The possible modes of QS with Hg²⁺ and Fe³⁺ are proposed. The addition of H₂PO₄^- caused the fluorescence of QS-Fe recover, indicating that QS can be used for cyclic detection of Fe³⁺. More importantly, the separation percentages of the solid QS for Hg²⁺and Fe³⁺ are 92.0% and 91.8% in aqueous solution, respectively, indicating that it has excellent ingestion capacity.
- barbituric acid derivatives,
- fluorescence sensor,
- iron ion,
- mercury ion,
- ion absorption
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

A Novel Fluorescent Sensor Based on Aryl-furfural Functionalized Barbituric Acid for Recognition and Separation of Hg2+/Fe3+

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通讯作者: 陈斌, bchen63@163.com

A Novel Fluorescent Sensor Based on Aryl-furfural Functionalized Barbituric Acid for Recognition and Separation of Hg²⁺/Fe³⁺