Citation: Zhang Maosheng, Linghu Lang, Zhang Jianyong, Nie Xuqiang, Li Xiaofei, Guo Dale, Xiao Shiji. Bibenzyl Derivatives from Dendrobium nobile[J]. Chinese Journal of Organic Chemistry, ;2019, 39(11): 3289-3293. doi: 10.6023/cjoc201903035 shu

Bibenzyl Derivatives from Dendrobium nobile

a.
School of Pharmacy, Zunyi Medical University, Zunyi, Guizhou 563006
b.
Guizhou Provincial Research Center for the Propagation and Efficient Utilization of Medicinal Orchids, Zunyi, Guizhou 563006
c.
School of Pharmacy, Chengdu University of Traditional Chinese Medicine, Chengdu 611137

Corresponding author: Xiao Shiji, xiaoshiji84@163.com
Received Date: 20 March 2019
Revised Date: 29 April 2019
Available Online: 2 November 2019
Fund Project: the National Natural Science Foundation of China 31560102Project supported by the National Natural Science Foundation of China (No. 31560102), and the Key Technologies R & D Program of Guizhou Province (No. QKH [2015]6010-2)the Key Technologies R & D Program of Guizhou Province QKH [2015]6010-2

Figures(3)

By silica gel, MCI column chromatographic and preparative high performance liquid chromatography (HPLC) technologies, three new bibenzyl derivatives were isolated from the tubes of Dendrobium nobile. One racemic compound was further purified by chiral (HPLC) to obtain a pair of enantiomers 1a and 1b, and the absolute configurations of the enantiomers were confirmed using electronic circular dichroism (ECD) calculations. By using spectroscopic techniques including NMR and HR-ESIMS, the structures of compounds 1~3 were identified as didendronbiline A (1), dendronbiline B (2), and dendronbiline C(3).
- dendrobium nobile,
- orchidaceae,
- bisbibenzyl,
- dendronbiline
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沈阳化工大学材料科学与工程学院沈阳 110142