Citation: Zhang Lingjuan, Dang Yujiao, Zhang Xianming. Diversified Synthesis of Imines via Aerobic Oxidation Catalyzed by Dinuclear Butterfly-Like Cu(Ⅰ) Complex[J]. Chinese Journal of Organic Chemistry, ;2019, 39(6): 1650-1654. doi: 10.6023/cjoc201903027 shu

Diversified Synthesis of Imines via Aerobic Oxidation Catalyzed by Dinuclear Butterfly-Like Cu(Ⅰ) Complex

Key Laboratory of Magnetic Molecules & Magnetic Information Materials, Ministry of Education, School of Chemical and Material Science, Shanxi Normal University, Linfen 041004

Corresponding author: Zhang Lingjuan, zhanglj@sxnu.edu.cn Zhang Xianming, zhangxm@dns.sxnu.edu.cn
Received Date: 15 March 2019
Revised Date: 3 April 2019
Available Online: 15 June 2019
Fund Project: the National Natural Science Foundation of China 21402112Project supported by the National Natural Science Foundation of China (No. 21402112), and the 1331 Project of Shanxi Province

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The selective catalytic oxidation of amines for the synthesis of imines is important both in laboratory and industrial production. From atom-efficient, economic and environmental view of points, dioxygen selective oxidation of amines was achieved by using wings-opened butterfly-like complex Cu₂(ophen)₂ as catalyst. It was worth noting that the catalytic system was efficient to the cross-coupling of alcohols with amines, homocoupling of primary amines and oxidative dehydrogenation of secondary amines. The yield is up to 93% and the selectivity of imines is as high as 99%. Avoiding the use of expensive nitroxyl derivatives and base was suitable for practical application.
- aerobic oxidation,
- dinuclear Cu-complex,
- base-free,
- N-O radical free,
- high selectivity
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