Citation: Shan He, Ling Li, Hu Jianfeng, Zhang Hao. Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes[J]. Chinese Journal of Organic Chemistry, ;2019, 39(6): 1548-1556. doi: 10.6023/cjoc201903012 shu

Application in the Asymmetric Catalytic Reactions of Chiral Cyclopentadienyl-Transition-Metal Complexes

Shan He ^a ,
Ling Li ^a ,
Hu Jianfeng ^a ,
Zhang Hao ^a,b,,

a.
College of Chemical & Chemical Engineering, Inner Mongolia University, Hohhot 010021
b.
Inner Mongolia Key Laboratory of Fine Organic Synthesis, Hohhot 010021

Corresponding author: Zhang Hao, haozhang@imu.edu.cn
Received Date: 6 March 2019
Revised Date: 26 April 2019
Available Online: 6 June 2019
Fund Project: the National Natural Science Foundation of China 21861028the Natural Science Foundation of Inner Mongolia 2017MS0206Project supported by the National Natural Science Foundation of China (No.21861028) and the Natural Science Foundation of Inner Mongolia (No. 2017MS0206)

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The chiral Cp ligands as stereocontrolling element of asymmetric catalytic reactions have attracted increasing attention. Particularly, designing and synthesizing more versatile chiral Cp ligands became one of the most interested research focuses in asymmetric catalysis. The complexes of various chiral Cp ligands with different transition metals that advanced in recent years, and the applications of these complexes in catalytic asymmetric reactions are reviewed in this paper.
- cyclopentadienyl ligands,
- asymmetric catalytic reactions,
- transition metal catalysis,
- synthesis
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