Citation: Zhang Xiang, Guo Caihong, Wu Haishun. Recent Developments of Homogeneous Transition-Metal Catalysts for Low Temperature Dehydrogenation of Methanol[J]. Chinese Journal of Organic Chemistry, ;2019, 39(9): 2458-2466. doi: 10.6023/cjoc201902032 shu

Recent Developments of Homogeneous Transition-Metal Catalysts for Low Temperature Dehydrogenation of Methanol

Key Laboratory of Magnetic Molecules, Magnetic Information Materials, Ministry of Education, School of Chemical and Material Science, Shanxi Normal University, Linfen 041004

Corresponding author: Guo Caihong, sxgch2006@163.com
Received Date: 26 February 2019
Revised Date: 27 March 2019
Available Online: 11 September 2019
Fund Project: the National Natural Science Foundation of China 21373131Project supported by the National Natural Science Foundation of China (No. 21373131)

Figures(9)

It is extremely urgent to develop green energy and find alternatives to fossil fuels since the energy shortage and environmental pollution become the worldwide concern. Methanol has emerged as a promising carrier for hydrogen storage owing to its high hydrogen density, simple structure and environmental friendly substance. The methanol reforming has triggered great efforts on the development of homogeneous catalysts, and the aim is to decrease methanol dehydrogenation reaction temperature and improve the selectivity. This review summarizes the recent research progresses in the homogeneously transition-metal catalyzed thermal dehydrogenation of methanol and aqueous methanol reforming. It mainly focuses on the structural characteristics of Ru, Rh, Ir, Fe and Mn-based complexes, catalytic reaction conditions, the reaction yield, and the catalytic reaction mechanism. The differences in the reactivities of these catalysts are analyzed and compared. Not only a summary is given, but also some perspectives and inspiration for improving the performance of aqueous methanol reforming catalysts for future research are discussed.
- methanol,
- C-H activation,
- dehydrogenation,
- homogeneous catalyst,
- Ru
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