Citation: Wu Fan, Huang Wenchao, Zhuo Kaiyue, Hua Yuhui, Lin Jianfeng, He Guomei, Chen Jiangxi, Nie Liming, Xia Haiping. Carbolong Complexes as Photothermal Materials[J]. Chinese Journal of Organic Chemistry, ;2019, 39(6): 1743-1752. doi: 10.6023/cjoc201901048 shu

Carbolong Complexes as Photothermal Materials

Wu Fan ^a ,
Huang Wenchao ^c ,
Zhuo Kaiyue ^b ,
Hua Yuhui ^b ,
Lin Jianfeng ^b ,
He Guomei ^a,, ,
Chen Jiangxi ^a ,
Nie Liming ^c,, ,
Xia Haiping ^b,,

a.
Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen 361005
b.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
c.
State Key Laboratory of Molecular Vaccinology and Molecular Diagnosis, Center for Molecular Imaging and Translational Medicine, School of Public Health, Xiamen University, Xiamen 361102

Corresponding author: He Guomei, gmhe@xmu.edu.cn Nie Liming, nielm@xmu.edu.cn Xia Haiping, hpxia@xmu.edu.cn
Received Date: 28 January 2019
Revised Date: 13 March 2019
Available Online: 21 June 2019
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21302158, U1705254, 21490573)the National Natural Science Foundation of China U1705254the National Natural Science Foundation of China 21490573the National Natural Science Foundation of China 21302158

Figures(7)

A series of photothermal cyclobutaosmapentalenes with conjugated groups attached to the metallacycle were synthesized from the reaction of OsCl₂(PPh₃)₃ with an organic multiyne and PPh₃, followed by a[2+2] cycloaddition with terminal alkynes. These highly conjugated metallacycles showed broad UV-Vis absorption and good photothermal efficiency. These easily synthesized metallacycles represent a type of new photothermal material.
- organometallics,
- metallacycle,
- photothermal
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沈阳化工大学材料科学与工程学院沈阳 110142