Citation: Hu Dan, Zhao Kunfeng, Tong Qin, He Dannong. Synthesis and Properties of Perfluorocyclobutyl Aryl Ether-Based Hydrophobic Polycarbonate[J]. Chinese Journal of Organic Chemistry, ;2019, 39(9): 2639-2644. doi: 10.6023/cjoc201812048 shu

Synthesis and Properties of Perfluorocyclobutyl Aryl Ether-Based Hydrophobic Polycarbonate

Hu Dan ^a ,
Zhao Kunfeng ^a,b,c ,
Tong Qin ^a,b,, ,
He Dannong ^a,b,c,,

a.
National Engineering Research Center for Nanotechnology, Shanghai 200241
b.
School of Material Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240
c.
Shanghai University of Medicine & Health Sciences, Shanghai 201318

Corresponding author: Tong Qin, tongqin_7557@163.com He Dannong, hdn_nercn@163.com
Received Date: 28 December 2018
Revised Date: 26 March 2019
Available Online: 11 September 2019
Fund Project: the Major National Scientific Research Projects 2015CB931902Project supported by the Major National Scientific Research Projects (No. 2015CB931902) and the Shanghai Science and Technology Development Funds (No. 16QB1402200)the Shanghai Science and Technology Development Funds 16QB1402200

Figures(9)

A novel hydrophobic polycarbonate containing perfluorocyclobutyl (PFCB) aryl ether was synthesized from commercially available p-methoxyphenol. The polymer exhibited excellent thermal stability and hydrophobicity without reducing the transparency of the material. The thermal decomposition temperature was 351℃ and the contact angle between the film and water was 110°. In order to further explore the effect of PFCB aryl ether structure on the properties of polycarbonate, a series of polycarbonates with different PFCB aryl ether group contents were synthesized from PFCB aryl ether monomer and bisphenol A monomer. By comparing their properties, the introduction of PFCB aryl ether structure into polycarbonate can reduce its dispersion and improve its thermal stability and hydrophobicity.
- polycarbonate,
- hydrophobicity,
- perfluorocyclobutyl aryl ether
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