Citation: Xu Lulu, Ye Qianwen, Cheng Dongping, Li Xiaonian, Xu Xiaoliang. Regioselective Ring-Opening Reaction of Cyclopropene Carboxylate Promoted by N-Bromosuccinimide[J]. Chinese Journal of Organic Chemistry, ;2019, 39(9): 2645-2649. doi: 10.6023/cjoc201812029 shu

Regioselective Ring-Opening Reaction of Cyclopropene Carboxylate Promoted by N-Bromosuccinimide

Xu Lulu ^a ,
Ye Qianwen ^a ,
Cheng Dongping ^b,, ,
Li Xiaonian ^a,, ,
Xu Xiaoliang ^a,,

a.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014
b.
College of Pharmaceutical, Zhejiang University of Technology, Hangzhou 310014

Corresponding author: Cheng Dongping, chengdp@zjut.edu.cn Li Xiaonian, xnli@zjut.edu.cn; xuxiaoliang@zjut.edu.cn Xu Xiaoliang, xuxiaoliang@zjut.edu.cn
Received Date: 16 December 2018
Revised Date: 28 March 2019
Available Online: 11 September 2019
Fund Project: the Zhejiang Provincial Natural Science Foundation of China LY18B020018the National Science Foundation of China 21602197Project supported by the Zhejiang Provincial Natural Science Foundation of China (Nos. LY18B020018, LY15B020004) and the National Science Foundation of China (No. 21602197)the Zhejiang Provincial Natural Science Foundation of China LY15B020004

Figures(1)

The cyclopropene compound contains an intra carbon-carbon double bond structure, which leads to distinctive active chemical reactivity due to the large ring tension. In this paper, the N-bromosuccinimide-promoted regioselective ring-opening of cyclopropene dicarboxylates to give functionalized α, β-unsaturated carboxylic acid ester compounds was studied. The reaction conditions are mild and the operation is simple.
- cyclopropene dicarboxylate,
- N-bromosuccinimide,
- ring-opening reaction
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