Citation: Liu Jianhui, Wang Xingyang. Potassium Phenyltrifluoroborate-Catalyzed Reduction of Aldehydes and Ketones into Alcohol with Silanes[J]. Chinese Journal of Organic Chemistry, ;2019, 39(5): 1411-1416. doi: 10.6023/cjoc201810010 shu

Potassium Phenyltrifluoroborate-Catalyzed Reduction of Aldehydes and Ketones into Alcohol with Silanes

Liu Jianhui ^a,b,, ,
Wang Xingyang ^a

a.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024
b.
School of Petroleum and Chemical Engineering, Dalian University of Technology, Panjin Campus, Panjin 124221

Corresponding author: Liu Jianhui, liujh@dlut.edu.cn
Received Date: 11 October 2018
Revised Date: 12 December 2018
Available Online: 18 May 2019
Fund Project: the State Key Laboratory of Fine Chemicals (Panjin) JH2014009Project supported by the State Key Laboratory of Fine Chemicals (Panjin) (No. JH2014009) and the Fundamental Research Funds for the Central Universities

The selective reduction of carbonyl group with organosilane as reducing agent was studied with methanol as a solvent under the action of 2.5 mol% C₆H₅BF₃K and 2.2 epuiv. (EtO)₃SiH. The target products were obtained in medium to high yield. This method shows good selectivity and provides a new method for carbonyl reduction.
- carbonyl reduction,
- organosilane,
- potassium phenyl trifluoroborate
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