Citation: Ma Hongpeng, Bai Chaolumen, Bao Yongsheng. Nano-Gold Catalyzed Transesterification of (Hetero) aryl Esters with Alkyl Halides via C-O Activation[J]. Chinese Journal of Organic Chemistry, ;2019, 39(3): 734-746. doi: 10.6023/cjoc201809027 shu

Nano-Gold Catalyzed Transesterification of (Hetero) aryl Esters with Alkyl Halides via C-O Activation

College of Chemistry and Environmental Science, Inner Mongolia Key Laboratory of Green Catalysis, Inner Mongolia Normal University, Hohhot 010022

Corresponding author: Bao Yongsheng, sbbys197812@163.com
Received Date: 21 September 2018
Revised Date: 1 November 2018
Available Online: 25 March 2018
Fund Project: the Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region NJYT-17-A22the National Natural Science Foundation of China 21861030the National Natural Science Foundation of China 21462031the Project of Inner Mongolia Normal University 2013ZRYB10Project supported by the National Natural Science Foundation of China (Nos. 21462031, 21861030), the Program for Young Talents of Science and Technology in Universities of Inner Mongolia Autonomous Region (No. NJYT-17-A22) and the Project of Inner Mongolia Normal University (No. 2013ZRYB10)

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Nano-gold catalyzed transesterification of the (hetero) aryl ester with alkyl halides via C-O activation has been developed. In a series of supported AuNPs and PdNPs, the Au/γ-Al₂O₃ catalyst with an AuNP mean diameter of 3.63 nm and 3 wt% Au loading exhibited the best catalytic performance. The catalyst can be reused and shows high activity after five cycles. The X-ray photoelectron spectroscopy (XPS) analysis of the catalyst before and after the reaction suggested that the reaction might be performed via a catalytic cycle that began with Au⁰.
- nano-gold catalyst,
- transesterification,
- halide
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