Citation: Fu Xiaofei, Zhao Wenxian. Progress in Difunctionalization of Alkenes[J]. Chinese Journal of Organic Chemistry, ;2019, 39(3): 625-647. doi: 10.6023/cjoc201808031 shu

Progress in Difunctionalization of Alkenes

Fu Xiaofei ^a ,
Zhao Wenxian ^a,b,,

a.
College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450000
b.
College of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000

Corresponding author: Zhao Wenxian, zhwx2595126@163.com
Received Date: 27 August 2018
Revised Date: 1 November 2018
Available Online: 25 March 2018
Fund Project: the Key Science Research of Education Committee in Henan Province 16A150020Project supported by the National Natural Science Foundation of China (Nos. 20972091, 21172139) and the Key Science Research of Education Committee in Henan Province (No. 16A150020)the National Natural Science Foundation of China 21172139the National Natural Science Foundation of China 20972091

Figures(95)

As an important kind of organic chemical reaction, difunctionalization of alkenes can not only synthesize multi-site reaction products effectively in one step, but also transform the starting material into other compounds that containing biological activity or drug activity. At the same time, it provides more methods for the construction of chemical structure diversity, so it is very important to develop the bifunctionalization of alkenes. In this paper, the bifunctionalization of various alkenes in recent 12 years is reviewed. It can be divided into three parts:copper-catalyzed difunctionalization of alkenes, other transition metal-catalyzed difunctionalization of alkenes, and non-metal-catalyzed difunctionalization of alkenes. The prospects of this reaction are also discussed.
- alkene,
- bifunctionalization,
- catalysis
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沈阳化工大学材料科学与工程学院沈阳 110142