Citation: Zhu Yangmin, Wang Zhonglong, Yang Jian, Xu Xu, Wang Shifa, Cai Zhengchun, Xu Haijun. N, N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu²⁺ and Ni²⁺ Ion[J]. Chinese Journal of Organic Chemistry, ;2019, 39(2): 427-433. doi: 10.6023/cjoc201807042 shu

N, N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu²⁺ and Ni²⁺ Ion

Zhu Yangmin ^a ,
Wang Zhonglong ^a ,
Yang Jian ^a ,
Xu Xu ^a ,
Wang Shifa ^a ,
Cai Zhengchun ^a ,
Xu Haijun ^a,b,,

a.
College of Chemical Engineering, Jiangsu Key Laboratory of Biomass-Based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037
b.
Jiangsu Key Laboratory for Biomass Energy and Material of Jiangsu Province, Nanjing 210042

Corresponding author: Xu Haijun, xuhaijun@njfu.edu.cn
Received Date: 23 July 2018
Revised Date: 25 September 2018
Available Online: 12 February 2018
Fund Project: Priority Academic Program Development of Jiangsu Higher Education Institutions PAPDProject supported by the Natural Science Foundation of Jiangsu Province No. BK20151513Fund from Jiangsu Key Laboratory for Biomass Energy and Material No. JSBEM201702Project supported by the Natural Science Foundation of Jiangsu Province (No. BK20151513), the Fok Ying Tung Education Foundation (No. 141030), the Fund from Jiangsu Key Laboratory for Biomass Energy and Material (No. JSBEM201702) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)Fok Ying Tung Education Foundation No. 141030

Figures(8)

A new turn-off probe 6 was synthesized from bis(pyridin-2-ylmethyl)amine and truxene derivatives, and its structure was confirmed by ¹H NMR and HRMS. The recognition behaviors of 6 to various metal ions were investigated and the results show that 6 exhibited good selectivity and high sensitivity to Cu²⁺ and Ni²⁺ with good anti-interference. The probe 6 presented apparent fluorescence quenching in DMF/H₂O (V/V=8/2, pH=7.0) solution toward Cu²⁺ and Ni²⁺. HRMS analysis showed a 1:1 binding stoichiometry between 6 and Cu²⁺ or Ni²⁺. The detection limit for Cu²⁺ and Ni²⁺ was calculated to be 28 and 41 nmol/L, respectively. The detection limit of 6 for Cu²⁺ and Ni²⁺ was far lower than the maximum allowable level of World Health Organization (WHO) limit for drinking water.
- truxene,
- bis(pyridin-2-ylmethyl)-amine (DPA),
- fluorescent sensor,
- Cu²⁺,
- Ni²⁺
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N, N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu2+ and Ni2+ Ion

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通讯作者: 陈斌, bchen63@163.com

N, N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu²⁺ and Ni²⁺ Ion