Citation: Liu Jing, Wan Cong, Zheng Aili, Wang Lianyue, Yin Kaiyue, Liu Dandan, Wang Shengde, Ren Lanhui, Gao Shuang. α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst[J]. Chinese Journal of Organic Chemistry, ;2019, 39(3): 811-820. doi: 10.6023/cjoc201807011 shu

α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst

Liu Jing ^a,† ,
Wan Cong ^a,† ,
Zheng Aili ^a ,
Wang Lianyue ^b ,
Yin Kaiyue ^a ,
Liu Dandan ^a ,
Wang Shengde ^a ,
Ren Lanhui ^a,, ,
Gao Shuang ^b,,

a.
College of Pharmacy, Weifang Medical University, Weifang 261053
b.
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023

Corresponding author: Ren Lanhui, Ren_lanhui@163.com Gao Shuang, sgao@dicp.ac.cn
Received Date: 5 July 2018
Revised Date: 4 September 2018
Available Online: 19 March 2018
Fund Project: the National Natural Science Foundation of China 21773227the National Natural Science Foundation of China 21773232Project supported by the National Natural Science Foundation of China (Nos. 21773227, 21773232)

Figures(7)

A catalytic system for the oxidation of benzylic ethers to esters has been developed utilizing reusable MnO_x-N@C as catalyst and tert-butyl hydroperoxide (TBHP) as benign oxidant under neat condition. The catalytic oxidation system has good functional groups tolerance and excellent chemoselectivity, and this catalytic procedure can also be scaled up.
- C-H bonds,
- oxidation,
- ether,
- ester,
- solvent-free
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α-Oxygenation of Benzylic Ethers to Esters Using MnOx-N@C Catalyst

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通讯作者: 陈斌, bchen63@163.com

α-Oxygenation of Benzylic Ethers to Esters Using MnO_x-N@C Catalyst