Citation: Yin Xiaoting, Li Wenjiong, Zhao Baoli, Cheng Kai. Research Progress on Silver-Catalyzed Decarboxylative Coupling Reaction[J]. Chinese Journal of Organic Chemistry, ;2018, 38(11): 2879-2887. doi: 10.6023/cjoc201805013 shu

Research Progress on Silver-Catalyzed Decarboxylative Coupling Reaction

Zhejiang Key Laboratory of Alternative Technologies for Fine Chemicals Process, Shaoxing University, Shaoxing 312000

Corresponding author: Cheng Kai, chengkai@usx.edu.cn
Received Date: 3 May 2018
Revised Date: 11 June 2018
Available Online: 16 November 2018
Fund Project: the Zhejiang Provincial Natural Science Foundation LY18B020006the Science Technology Project of Shaoxing City 2017B70053Project supported by the National Natural Science Foundation of China (No. 21402123), the Zhejiang Provincial Natural Science Foundation (No. LY18B020006, LQ15B020002) and the Science Technology Project of Shaoxing City (No. 2017B70053)the Zhejiang Provincial Natural Science Foundation LQ15B020002the National Natural Science Foundation of China 21402123

Figures(6)

Transition-metal-catalyzed decarboxylative cross-coupling reactions have been well developed as efficient synthetic methods in organic synthesis. Herein the new application of silver-catalyzed decarboxylation in Hunsdiecker-type halogenation, carbon-carbon bond formation, carbon-heteratom bond formation and C-H bond functionalization reaction is discussed. The recent progress in silver-catalyzed decarboxylative coupling reaction with aliphatic carboxylic acids, α-keto acids and aryl carboxylic acid is reviewed. With the assistance of peroxides, selective decarboxylative coupling reaction could be proceeded via free-radical process by silver catalysis. The controlled free-radical transformation is operational simplification without the exclusion of water and oxygen under mild conditions.
- silver-catalyzed,
- aliphatic carboxylic acid,
- α-keto acid,
- aryl carboxylic acid,
- coupling reacion,
- free-radical process
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