Citation: Jiang Shaoliang, Liu Jie, Cui Yanhong, Wu Huabiao, Han Liang. Syntheses and Photovoltaic Performance of Nitrogen-Containing Rigid Heterocycle Substituted Coumarin Sensitizing Dyes[J]. Chinese Journal of Organic Chemistry, ;2018, 38(12): 3219-3226. doi: 10.6023/cjoc201805007 shu

Syntheses and Photovoltaic Performance of Nitrogen-Containing Rigid Heterocycle Substituted Coumarin Sensitizing Dyes

a.
College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310017
b.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310017

Corresponding author: Han Liang, hanliang814@163.com
Received Date: 2 May 2018
Revised Date: 20 July 2018
Available Online: 23 December 2018
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21406202)the National Natural Science Foundation of China 21406202

Figures(7)

Two novel nitrogen-containing rigid heterocycle substituted coumarin sensitizing dyes were designed and synthesized with nitrogen-containing rigid heterocycle substituted coumarin as the electron donor, biphenyl or phenylthiophene as π bridge and cyanoacrylic acid as the electron acceptor. Their spectral properties, charge recombination rate and photovoltaic performance were compared with those of the corresponding diethylaminocoumarin sensitizing dyes. The results show that the incorporation of nitrogen-containing rigid heterocycle leads to the broadening of the absorption spectrum and the improvement of light-harvesting ability. In the dye with phenylthiophene as π bridge, the presence of nitrogen-containing rigid heterocycle distinctly weakens the molecular planarity, decreases the charge recombination rate and improves V_OC. Therefore, among four coumarin sensitizing dyes, nitrogen-containing rigid heterocycle coumarin sensitizing dye with phenylthiophene π bridge exhibits the optimal photoelectric conversion efficiency 3.89% due to its better J_SC, highest V_OC and fill factor (ff).
- coumarin,
- dye sensitizer,
- nitrogen-containing rigid heterocylce,
- synthesis,
- photoelectric conversion efficiency
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