Citation: Hao Yunpeng, Xie Zhengfeng, Bao Wanrui, Wang Xin, Shi Wei. Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide[J]. Chinese Journal of Organic Chemistry, ;2018, 38(8): 2109-2115. doi: 10.6023/cjoc201804034 shu

Synthesis and Properties of a Novel Colorimetric and Fluorescent Turn-On Sensor for Cyanide

Hao Yunpeng ^a ,
Xie Zhengfeng ^a,b,, ,
Bao Wanrui ^b ,
Wang Xin ^b ,
Shi Wei ^a,,

a.
College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500
b.
College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046

Corresponding author: Xie Zhengfeng, xiezhf@swpu.edu.cn Shi Wei, shiwei80@swpu.edu.cn
Received Date: 17 April 2018
Revised Date: 15 May 2018
Available Online: 24 August 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21262034, 21364013), the Youth Science and Technology Innovation Team of Southwest Petroleum University (No.2017CXTD05)the National Natural Science Foundation of China 21262034the Youth Science and Technology Innovation Team of Southwest Petroleum University 2017CXTD05the National Natural Science Foundation of China 21364013

Figures(12)

A novel fluorescent "turn-on" probe 7-(dibutylamino)-2'-((2-hydroxybenzylidene)amino)-3-methyl-1-phenyl-1H-spiro[chromeno[2, 3-c]pyrazole-4, 1'-isoindolin]-3'-one (SCPz-S) with Schiff base structure was designed and synthesized, and characterized by ¹H NMR, ¹³C NMR and high resolution mass spectrometry (HRMS). The UV-Vis and fluorescence spectra were used to investigate the ions recognition capability of probe SCPz-S. It was excavated that the probe SCPz-S has a dual colorimetric and fluorescence response to CN^- in THF/H₂O (V:V=1930:50, 5 mmol/L Tris-HCl, pH=7.4). After adding CN^-, the system of probe SCPz-S will change from colorless to yellow, and fluorescence enhance 1060-fold at 575 nm. The sensor SCPz-S also has good anti-interference ability and a wide pH range from 3 to 12 applicable. Its LOD for CN^- is 1.121×10^-8 mol/L, and the recognition mechanism has been investigated.
- spiro[chromene[2, 3-c]pyrazole-4, 1'-isoindoline],
- fluorescence,
- colorimetric,
- CN^-,
- Schiff base,
- deprotonation
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