Citation: Pang Chuming, Luo Shihe, Hao Zhifeng, Gao Jian, Huang Zhaohao, Yu Jiahai, Yu Simin, Wang Zhaoyang. Synthesis and Fluorescent Sensing Application of Porous Organic Polymer Materials[J]. Chinese Journal of Organic Chemistry, ;2018, 38(10): 2606-2624. doi: 10.6023/cjoc201804009 shu

Synthesis and Fluorescent Sensing Application of Porous Organic Polymer Materials

Pang Chuming ^a ,
Luo Shihe ^a ,
Hao Zhifeng ^b,, ,
Gao Jian ^a ,
Huang Zhaohao ^a ,
Yu Jiahai ^a ,
Yu Simin ^a ,
Wang Zhaoyang ^a,,

a.
Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006
b.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006

Corresponding author: Hao Zhifeng, haozhifeng3377@163.com Wang Zhaoyang, wangzy@scnu.edu.cn
Received Date: 5 April 2018
Revised Date: 15 May 2018
Available Online: 5 October 2018
Fund Project: the Applied Science and Technology Research and Development Special Foundation of Guangdong Province 2016B090930004the Undergraduates Innovation Project of South China Normal University 20181415the Guangzhou Science and Technology Project Scientific Special 201607010251the Guangdong Provincial Science and Technology Project 2017A010103016the Natural Science Foundation of Guangdong Province 2014A030313429Project supported by the Undergraduates Innovation Project of South China Normal University (No. 20181415), the Natural Science Foundation of Guangdong Province (No. 2014A030313429), the Guangzhou Science and Technology Project Scientific Special (No. 201607010251), the Applied Science and Technology Research and Development Special Foundation of Guangdong Province (No. 2016B090930004) and the Guangdong Provincial Science and Technology Project (No. 2017A010103016)

Figures(5)

Porous organic polymer fluorescence materials have the characteristics of high porosity and outstanding fluorescence properties. The function of fluorescence sensing is given when the skeleton has binding sites with specific analytes, such as nitroaromatic explosives (NAEs), metal ions, anions, gases, organic solvents, etc. In this paper, according to the different types of porous organic polymer materials (POPs), namely the amorphous porous organic polymer materials, crystal porous metal organic framework materials (MOFs) containing coordination bond, and crystal covalent organic framework materials (COFs), the new progress of the POPs fluorescence materials in recent years is reviewed. Especially, the design and synthesis based on functional organic molecules, and their fluorescence sensing applications, are introduced in details. In the future, continuing to design new types of fluorescent COFs from the molecular level is a development direction of highly efficient and recyclable fluorescence chemosensors for detecting NAEs, metal ions, anions, etc.
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