Citation: Chen Zhikang, Mao Yuanhong, Cao Yucai, Liang Shengbiao, Song Sha, Ni Chen, Liu Zhenyu, Ye Xiaofeng, Shen An, Zhu Hongping. Metallocene Catalyst Systems and Control over the Propylene Polymerization[J]. Chinese Journal of Organic Chemistry, ;2018, 38(11): 2937-2992. doi: 10.6023/cjoc201803047 shu

Metallocene Catalyst Systems and Control over the Propylene Polymerization

Chen Zhikang ^a ,
Mao Yuanhong ^b ,
Cao Yucai ^c ,
Liang Shengbiao ^b,, ,
Song Sha ^c ,
Ni Chen ^b ,
Liu Zhenyu ^b ,
Ye Xiaofeng ^c ,
Shen An ^c ,
Zhu Hongping ^a,,

a.
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005
b.
Sinopec Maoming Petrochemical Company, Maoming 525011
c.
State Key Laboratory of Polyolefins and Catalysis, Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai Research Institute of Chemical Industry, Shanghai 200062

Corresponding author: Liang Shengbiao, liangshengb.mmsh@sinopec.com Zhu Hongping, hpzhu@xmu.edu.cn
Received Date: 27 March 2018
Revised Date: 27 May 2018
Available Online: 15 November 2018
Fund Project: the Program for Innovative Research Team of Education IRT_14R31the National Natural Science Foundation of China 20673191Project supported by the Sinopec Maoming Petrochemical Company, the State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins (Nos. 201501-PT-C01-005, CXY-2015-003, 16DZ2270800, 16DZ2290700), the National Natural Science Foundation of China (Nos. 21473142, 20673191), and the Program for Innovative Research Team of Education (No. IRT_14R31)the National Natural Science Foundation of China 21473142the State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins 16DZ2290700the State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins CXY-2015-003the State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins 201501-PT-C01-005the State Key Laboratory of Polyolefins and Catalysis and Shanghai Key Laboratory of Catalysis Technology for Polyolefins 16DZ2270800

Figures(15)

While the metallocene catalysts were widely used to produce the metallocene polypropylenes (mPP) in other countries, the traditional Ziegler-Natta catalyst has still been dominantly employed for manufacturing the polypropylenes (PP) in our country at current time. The property of the mPP appears more improved than that of the PP produced by the Ziegler-Natta catalyst, and the market demand for the mPP is worldwidely increasing every year. Therefore, it is urgent to develop the metallocene catalysts for the industrial use in domestic companies. The metallocene catalysts are of versatile structures, which are able to show more exact control over the propylene polymerization activity and the polypropylene stereostructures than the Ziegler-Natta catalyst, and thus catalyze to generate new PPs of the diverse structures. This manuscript will give a detailed summary on the metallocene catalysts so far reported. The important factors such as temperature, propylene pressure, catalyst concentration, cocatalyst types and so on will be illustrated, which all have significant influence on the catalytic reaction activity. The reaction mechanism will be discussed as well.
- metallocene catalyst,
- propylene polymerization,
- reaction mechanism,
- structural control,
- stereostructure of the polypropylenes,
- structure and property correalation
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