Citation: Zhang Wei, Deng Wei. β-Cyclodextrin Modified Gold Nanoparticles: Catalytic Applications and Molecular Selectivity[J]. Chinese Journal of Organic Chemistry, ;2018, 38(11): 3002-3008. doi: 10.6023/cjoc201803038 shu

β-Cyclodextrin Modified Gold Nanoparticles: Catalytic Applications and Molecular Selectivity

Zhang Wei ^a ,
Deng Wei ^a,b,,

a.
School of Materials Science and Engineering, Shanghai University, Shanghai 200444
b.
School of Chemical and Engineering, Shanghai Institute of Technology, Shanghai 201418

Corresponding author: Deng Wei, wdeng@shu.edu.cn
Received Date: 25 March 2018
Revised Date: 3 July 2018
Available Online: 24 November 2018
Fund Project: the Shanghai Municipal Education Commission (Plateau Discipline Construction Program), the National Science Foundation of China 21601125the Shanghai Municipal Education Commission (Plateau Discipline Construction Program), the National Science Foundation of China 21174081the Shuguang Scholar Project and Start-up Funding of Shanghai Institute of Technology YJ-201610the Natural Science Foundation of Shanghai City 16ZR1435700Project supported by the Shanghai Municipal Education Commission (Plateau Discipline Construction Program), the National Science Foundation of China (Nos. 21601125, 21174081), the Natural Science Foundation of Shanghai City (No. 16ZR1435700), the Shuguang Scholar of Shanghai Municipal Education Commission (No. 16SG49), the Shuguang Scholar Project and Start-up Funding of Shanghai Institute of Technology (No. YJ-201610)the Shuguang Scholar of Shanghai Municipal Education Commission 16SG49

Figures(7)

L-Cys-β-CD@AuNPs nanoparticles were synthesized by a simple method of the reduction of HAuCl₄ with NaBH₄and L-Cys-CD. The catalytic activity of L-Cys-β-CD@AuNPs nanoparticles for the catalytic reductions of 4-nitrophenol and 4-nitro-1-naphthol was researched in detail. Because of the selective binding of β-cyclodextrin (β-CD) to different guest molecules, L-Cys-β-CD@AuNPs exhibits diverse catalytic activities for different substrates. The experimental results prove that L-Cys-β-CD@AuNPs shows better catalytic efficiency for the reduction of 4-nitro-1-naphthol than p-nitrophenol.
- β-cyclodextrin,
- catalysis,
- gold nanoparticles,
- molecular selectivity,
- organic-inorganic hybrid materials
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