Citation: Fu Yufang, Zou Zhijuan, Tang Cheng, Song Kunpeng. A Red Bayberry Shape Monodisperse Microsphere Support Pd Nanoparticles for Suzuki-Miyaura Cross-Coupling Reaction at Room Temperature[J]. Chinese Journal of Organic Chemistry, ;2018, 38(11): 3106-3111. doi: 10.6023/cjoc201803027 shu

A Red Bayberry Shape Monodisperse Microsphere Support Pd Nanoparticles for Suzuki-Miyaura Cross-Coupling Reaction at Room Temperature

Fu Yufang ^a ,
Zou Zhijuan ^a ,
Tang Cheng ^a ,
Song Kunpeng ^a,b,,

a.
College of Chemistry and Chemical Engineering, China West Normal University, Nanchong 637002
b.
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, Nanchong 637002

Corresponding author: Song Kunpeng, song19880405@126.com
Received Date: 17 March 2018
Revised Date: 8 June 2018
Available Online: 16 November 2018
Fund Project: the Meritocracy Research Funds of China West Normal University 17Y031the Fundamental Research Funds of China West Normal University 17C038the National Undergraduate Training Program for Innovation and Entrepreneurship 201710638031Project supported by the National Undergraduate Training Program for Innovation and Entrepreneurship (No. 201710638031), the Fundamental Research Funds of China West Normal University (No. 17C038) and the Meritocracy Research Funds of China West Normal University (No. 17Y031)

Figures(7)

In this study, a controlled synthesis of hyper-crosslinked monodisperse microsphere with homogeneous mesoporous aperture about 6 nm is presented. After supported with palladium, the catalyst was performed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and nitrogen adsorption and desorption surface area analyses. The results showed that HCP-(PS-DVB)-Pd(0) possessed high catalytic activity for Suzuki-Miyaura cross-coupling reaction at room temperature, and the catalyst also show excellent reusability. After recycled for 10 times, the yield can maintain above 95% and the surface areas can still reach 480.5 m²·g^-1. These results suggest that the HCP-(PS-DVB)-Pd(0) catalyst has potential applications in synthetic and industrial chemistry.
- hyper-crosslinked PS-DVB,
- monodisperse microsphere,
- Pd nanoparticles catalyst,
- Suzuki cross-coupling reaction
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