Citation: Yang Xiaojiang, Mao Jincheng, Zhang Heng, Zhang Yang, Mao Jinhua. Copper-Catalyzed Aerobic Oxidation Reaction of Benzyl Alcohol in Water under Base-Free Condition[J]. Chinese Journal of Organic Chemistry, ;2018, 38(10): 2780-2783. doi: 10.6023/cjoc201802018 shu

Copper-Catalyzed Aerobic Oxidation Reaction of Benzyl Alcohol in Water under Base-Free Condition

State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500

Corresponding author: Mao Jincheng, jcmao@swpu.edu.cn
Received Date: 12 February 2018
Revised Date: 13 April 2018
Available Online: 1 October 2018
Fund Project: the National High Technology Research & Development Program 2016ZX05053Project supported by the Sichuan Youth Science & Technology Foundation (No. 2017JQ0010), the National High Technology Research & Development Program (No. 2016ZX05053), the Key Fund Project of Educational Commission of Sichuan Province (No. 16CZ0008), the Explorative Project Fund of the State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Southwest Petroleum University) (No. G201601)the Key Fund Project of Educational Commission of Sichuan Province 16CZ0008the Explorative Project Fund of the State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Southwest Petroleum University) G201601the Sichuan Youth Science & Technology Foundation 2017JQ0010

Figures(2)

A green and very mild method for the oxidation of benzyl alcohols to aromatic aldehydes with excellent conversions has been developed. The reaction could be carried out directly in air at room temperature and was catalyzed by bis (8-quinolinolato) copper (Ⅱ) with 2, 2, 6, 6-tetramethylpiperidine-1-oxyl (TEMPO) as co-catalysts. The methodology provided a practical approach for the synthesis of aromatic aldehydes, which has the advantages of environment-friendly, simple workup and high yields.
- benzyl alcohol,
- aromatic aldehyde,
- copper,
- TEMPO,
- aerobic oxidation
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