Citation: Cai Cheng, Sun Kaifang, Wang Ying, Hou Zongsheng, Ren Qizhi. Synthesis, Properties and Photocatalysis for 2, 3-Dihydroxy-naphthalene of Water-Soluble Sulfonated Porphyrins[J]. Chinese Journal of Organic Chemistry, ;2018, 38(7): 1733-1739. doi: 10.6023/cjoc201802009 shu

Synthesis, Properties and Photocatalysis for 2, 3-Dihydroxy-naphthalene of Water-Soluble Sulfonated Porphyrins

School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240

Corresponding author: Ren Qizhi, qzren@sjtu.edu.cn
Received Date: 6 February 2018
Revised Date: 8 March 2018
Available Online: 29 July 2018
Fund Project: the National Natural Science Foundation of China 21371120Project supported by the National Natural Science Foundation of China (No. 21371120)

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A series of water-soluble sulfonated porphyrins have been synthesized and characterized by ¹H NMR, IR, UV-Vis, fluorescence and MS. The fluorescence quantum yield and lifetime of the series of porphyrins have been obtained. These porphyrins have been used as photocatalysts for the oxidation of 2, 3-dihydroxynaphthalene. The main product has been proved to be 1, 2-benzenedicarboxylic acid with the highest conversion rate of 91%. The effects of electron caused by different substituent groups and steric structure on sulfonated porphyrins photocatalytic activities have been investigated. It has been proved that substituent groups have electronic effects on the photocatalytic activities. The chosen of oxygen resource, the kinetics of the oxidation and the photocatalytic mechanism of sulfonated porphyrins have been investigated.
- sulfonated porphyrin,
- electronic effect,
- photocatalytic activity,
- kinetics
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