Citation: Wang Jingjing, Li Feng, Yu Xiaobo, Liu Lantao, Ding Junru, Xie Peiyao, Wang Jianhui. Recent Progress in the Research of the Transition-Metal-Catalyzed N-Directed Carbonyl and Alcohol Hydroxyl ortho C—C Bonds Activation Reactions[J]. Chinese Journal of Organic Chemistry, ;2018, 38(7): 1638-1649. doi: 10.6023/cjoc201802007 shu

Recent Progress in the Research of the Transition-Metal-Catalyzed N-Directed Carbonyl and Alcohol Hydroxyl ortho C—C Bonds Activation Reactions

a.
Henan Engineering Laboratory of Green Synthesis for Pharmaceuticals, School of Chemistry and Chemical Engineering, Shangqiu Normal University, Shangqiu 476000
b.
Department of Chemistry, College of Science, Tianjin University, Tianjin 300072
c.
College of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022

Corresponding author: Wang Jianhui, wangjingjing0918@163.com
Received Date: 4 February 2018
Revised Date: 3 March 2018
Available Online: 16 July 2018
Fund Project: Project supported by the National Natural Sciences Foundation of China (Nos. 21402116, 21502111), the Key Scientific and Technological Project of Henan Province (No. 172102210099) and the Key Science Research of Education Committee in Henan Province (No. 15A150072)the National Natural Sciences Foundation of China 21402116the Key Scientific and Technological Project of Henan Province 172102210099the National Natural Sciences Foundation of China 21502111the Key Science Research of Education Committee in Henan Province 15A150072

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Transition-metal-catalyzed C—C bond cleavage has been considered as one of the most interesting subject and challenging area in organometallic chemistry. The recent progress of transition-metal-catalyzed (Rh, Ni, Pd and Ru) nitrogen atom chelation-assisted C—C activation and controlled transformation is reviewed, and the mechanisms of these C—C activation reactions are also discussed.
- C—C bond activation,
- reductive elimination,
- transition metals,
- metalation
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