Citation: Li Zhijuan, Jian Hui, Wang Weihua, Wang Qiang, He Lin. Insertion Reaction of Benzynes and Stable Sulfur Ylide[J]. Chinese Journal of Organic Chemistry, ;2018, 38(8): 2045-2053. doi: 10.6023/cjoc201802003 shu

Insertion Reaction of Benzynes and Stable Sulfur Ylide

School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832000

Corresponding author: He Lin, helin@shzu.edu.cn
Received Date: 2 February 2018
Revised Date: 23 April 2018
Available Online: 3 August 2018
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21462034)the National Natural Science Foundation of China 21462034

Figures(3)

Benzynes undergo insertion reaction with C=S bond of the stable sulfur ylide through a cascade[2+2] cycloaddition and ring-opening reaction to construct a new C-S bond, producing ortho-substituted aryl-alkyl thioether derivatives in moderate to good yields.
- benzyne,
- sulfur ylide,
- insertion reaction,
- C-S bond
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