Citation: Hou Yadong, Pang Haixia, Yang Chao, Hui Yonghai. Mesoporous MCM-41 Supported Schiff Base-Cu(ClO₄)₂·6H₂O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives[J]. Chinese Journal of Organic Chemistry, ;2018, 38(8): 2036-2044. doi: 10.6023/cjoc201801039 shu

Mesoporous MCM-41 Supported Schiff Base-Cu(ClO₄)₂·6H₂O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives

Hou Yadong ^a ,
Pang Haixia ^a ,
Yang Chao ^a,, ,
Hui Yonghai ^a,b,,

a.
Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education & Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046
b.
School of Chemistry and Chemistry Engineering, Lingnan Normal University, Zhanjiang 524048

Corresponding author: Yang Chao, jerryyang1924@163.com Hui Yonghai, hyhai97@126.com
Received Date: 26 January 2018
Revised Date: 18 April 2018
Available Online: 3 August 2018
Fund Project: Project supported by the National Natural Science Foundation of China (Nos. 21362036, 51564045)the National Natural Science Foundation of China 51564045the National Natural Science Foundation of China 21362036

Figures(8)

Herein, Michael addition-condensation of isatin-3-imines with mercaptoacetic acid to afford a new simple and efficient synthesis of spiro[indole-thiazolidine] derivatives in high yield (up to 99%) by using of MCM-41@Schiff base-Cu(ClO₄)₂·6H₂O as heterogeneous catalyst is reported. In addition, it is found that heterogeneous catalyst exhibits better activity than homogeneous catalyst in the same functional groups. The effect of the pore structure on mesoporous molecular sieve nanoreactor MCM-41 for this reaction is further explored. Consistent activity of recovered catalyst was found to be almost same up to six cycles in 93% yield.
- MCM-41,
- heterogeneous catalyst,
- spiro[indole-thiazolidine],
- nano-reactors
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Mesoporous MCM-41 Supported Schiff Base-Cu(ClO4)2·6H2O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives

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通讯作者: 陈斌, bchen63@163.com

Mesoporous MCM-41 Supported Schiff Base-Cu(ClO₄)₂·6H₂O Catalyzed Synthesis of Spiro[indole-thiazolidine] Derivatives