Citation: Qiu Huihua, Cheng Borui, Huang Yingsi, Chen Cui, Zhou Peng. Research on the Tandem Reaction via Chloropalladation/Heck Cross Coupling of o-(Alkynyl)styrenes with Pd/O₂[J]. Chinese Journal of Organic Chemistry, ;2018, 38(7): 1817-1822. doi: 10.6023/cjoc201801030 shu

Research on the Tandem Reaction via Chloropalladation/Heck Cross Coupling of o-(Alkynyl)styrenes with Pd/O₂

School of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming 525000

Corresponding author: Qiu Huihua, qh198511@163.com
Received Date: 23 January 2018
Revised Date: 26 March 2018
Available Online: 12 July 2018
Fund Project: the National Natural Science Foundation of China 21602035Project supported by the National Natural Science Foundation of China (No. 21602035) and the Natural Science Foundation of Guangdong Province (No. 2016A030307030)the Natural Science Foundation of Guangdong Province 2016A030307030

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An economic and environmental synthestic method for 3-chloroindenes from o-(alkynyl)styrenes through tandem reactions including choropalladation/Heck cross coupling in Pd/O₂ system was reported. Taking green dioxygen as sole oxidant and LiCl as chlorine source, 13 functionalized 3-chloroindenes could be synthesized in moderate to high yield without the addition of CuCl₂
- Pd-catalyzed,
- dioxygen,
- chloropalladation,
- indene
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沈阳化工大学材料科学与工程学院沈阳 110142

Research on the Tandem Reaction via Chloropalladation/Heck Cross Coupling of o-(Alkynyl)styrenes with Pd/O2

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通讯作者: 陈斌, bchen63@163.com

Research on the Tandem Reaction via Chloropalladation/Heck Cross Coupling of o-(Alkynyl)styrenes with Pd/O₂