Citation: Zhang Zhenbei, Sun Wei, Cao Zhishan. Progress in Activation of Small Molecules Promoted by Frustrated Lewis Pairs[J]. Chinese Journal of Organic Chemistry, ;2018, 38(6): 1292-1318. doi: 10.6023/cjoc201801003 shu

Progress in Activation of Small Molecules Promoted by Frustrated Lewis Pairs

Zhang Zhenbei ^a,b,, ,
Sun Wei ^b ,
Cao Zhishan ^c

a.
College of Chemistry & Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003
b.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
c.
College of Animal Science and Veterinary Medicine, Henan Institute of Science and Technology, Xinxiang 453003

Corresponding author: Zhang Zhenbei, zhenbei.zhang@hist.edu.cn
Received Date: 3 January 2018
Revised Date: 26 February 2018
Available Online: 8 June 2018
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21473226)the National Natural Science Foundation of China 21473226

Figures(72)

Frustrated Lewis pairs (FLPs) chemistry has grown rapidly during the last decade and provided a new strategy for the activation of a variety of small molecules, such as hydrogen, olefins, alkynes, carbon dioxide, tetrahydrofuran and hydrosilane etc. The activations of these molecules have probided a new method in the utility of main group element. The structure and reactivity of FLPs are reviewed and the recent progress in activation of small molecules promoted by frustrated Lewis pairs is introduced.
- frustrated Lewis pairs,
- B (C₆F₅)₃,
- metal-free catalysis,
- organic synthesis
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