Citation: Lin Yamei, Yi Wenbin. A Route to Alkynyl Sulfides and Asymmetric Disulfides from Sodium Arylsulfiniate[J]. Chinese Journal of Organic Chemistry, ;2018, 38(5): 1207-1213. doi: 10.6023/cjoc201711036 shu

A Route to Alkynyl Sulfides and Asymmetric Disulfides from Sodium Arylsulfiniate

Lin Yamei ,
Yi Wenbin ^,

Chemical Engineering College, Nanjing University of Science & Technology, Nanjing 210094

Corresponding author: Yi Wenbin, yiwb@njust.edu.cn
Received Date: 21 November 2017
Revised Date: 17 December 2017
Available Online: 10 May 2018
Fund Project: the Fundamental Research Funds for the Central Universities 30916011102the National Natural Science Foundation of China 21776138Project supported by the National Natural Science Foundation of China (Nos. 21776138, 21476116), the Fundamental Research Funds for the Central Universities (No. 30916011102) and the Qing Lan and Six Talent Peaks in Jiangsu Provincethe National Natural Science Foundation of China 21476116

Figures(1)

A new approach for the synthesis of alkynyl sulfides and asymmetric disulfides with odorless, easy-to-handle sodium arylsulfiniates as the sulfur source in I₂/PPh₃ aqueous system has been developed. Compared with reported approaches, this protocol provides several merits including simple procedures, free of transition-metal catalysts and organic solvent, and high yields.
- reaction in water,
- sodium arylsulfiniate,
- alkynyl sulfide,
- asymmetric disulfide
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