Citation: Jiang Hua, Li Qiaolian, Wang Guangxia. Progress in Helicates Directed by Metal Coordination[J]. Chinese Journal of Organic Chemistry, ;2018, 38(5): 1065-1084. doi: 10.6023/cjoc201711013 shu

Progress in Helicates Directed by Metal Coordination

a.
School of Chemical and Environmental Engineering, Wuyi University, Jiangmen 529020
b.
Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
c.
College of Chemistry, Beijing Normal University, Beijing 100875
d.
Engineering Research Center for Nanomaterials, Henan University, Kaifeng 475004

Corresponding author: Jiang Hua, jiangh@bnu.edu.cn
Received Date: 7 November 2017
Revised Date: 23 November 2017
Available Online: 15 May 2017
Fund Project: the National Natural Science Foundation of China 21332008the National Natural Science Foundation of China 21472015Project supported by the National Natural Science Foundation of China (Nos. 21472015, 21332008)

Figures(41)

Artificial foldamers were constructed by non-covalent interactions to mimic the structures of biomacromolecules, such as proteins and DNA, which is conducive to a better understanding of the chemical processes at the molecular level in nature. The significant advances in foldamers render it become one of the most important topics in supramolecular chemistry. Coordination bond is widely used in the self-assembly process due to its bond strength and diverse geometry. In this article, we summarize a few types of metal-coordination helical folding systems, including single helicate, double helicates, triple helicates, quadruple helicates and cyclic helicates, and their folding behaviors and structural reconfiguration in the coordination process.
- foldamers,
- helicates,
- metal ions,
- coordination,
- structural reconfiguration
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沈阳化工大学材料科学与工程学院沈阳 110142