Citation: Yu Haiyang, Pi Chao, Wang Yong, Cui Xiuling, Wu Yangjie. Iodine-Catalyzed Regioselective Sulfonylation of Quinoline N-Oxides with Sulfonyl Hydrazides[J]. Chinese Journal of Organic Chemistry, ;2018, 38(1): 124-130. doi: 10.6023/cjoc201709054 shu

Iodine-Catalyzed Regioselective Sulfonylation of Quinoline N-Oxides with Sulfonyl Hydrazides

Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450052

Corresponding author: Cui Xiuling, cuixl@zzu.edu.cn
Received Date: 30 September 2017
Revised Date: 14 November 2017
Available Online: 15 January 2017
Fund Project: the Ministry of Science and Technology of China 2016YFE0132600Project supported by the Ministry of Science and Technology of China (No. 2016YFE0132600) and the Science and Technology Innovation Program of Universities in Henan Province (No. 16HASTIT007)the Science and Technology Innovation Program of Universities in Henan Province 16HASTIT007

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A novel and simple protocol has been developed for the regioselective sulfonylation of quinolone N-oxides at their C-2 postition. This method features with a simple system, high efficiency, environmental friendliness, and metal-free conditions. Aliphatic and aryl sulfonyl hydrazides smoothly undergo sulfonylation with quinoline N-oxides in good yields.
- iodine-catalyzed,
- quinoline N-oxides,
- sulfonyl hydrazides
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