Citation: Feng Shan'e, Hua Lu, Yao Zhigang, Xu Fan. Syntheses of 2-Amino-3, 1-benzothiazines Catalyzed by Cationic Ytterbium Complex[J]. Chinese Journal of Organic Chemistry, ;2017, 37(12): 3257-3261. doi: 10.6023/cjoc201709043 shu

Syntheses of 2-Amino-3, 1-benzothiazines Catalyzed by Cationic Ytterbium Complex

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123

Corresponding author: Xu Fan, xufan@suda.edu.cn
Received Date: 26 September 2017
Revised Date: 23 October 2017
Available Online: 15 December 2017
Fund Project: the National Natural Science Foundation of China 21272168Project supported by the National Natural Science Foundation of China (No. 21272168)

Figures(2)

2-Amino-3, 1-benzothiazine and its functionalized derivatives are known as useful compounds with a range of biological applications. A highly efficient reaction of o-aminocinnamate and isothiocyanates catalyzed by cationic ytterbium complex[Yb(CH₃CN)₉]³⁺[(AlCl₄)₃]^3-·CH₃CN under mild and solvent-free conditions was developed, which provides 2-amino-3, 1-benzothiazines in high yields and chemoselectivity.
- cationic complex,
- ytterbium,
- catalysis,
- 2-amino-3, 1-benzothiazine
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