Citation: Kong Shengnan, Malik Abaid Ullah, Qian Xuefeng, Shu Mouhai, Xiao Wende. Asymmetric Hydrogenation of β-Keto Esters Catalyzed by Ruthenium Species Supported on Porous Organic Polymer[J]. Chinese Journal of Organic Chemistry, ;2018, 38(3): 656-664. doi: 10.6023/cjoc201709018 shu

Asymmetric Hydrogenation of β-Keto Esters Catalyzed by Ruthenium Species Supported on Porous Organic Polymer

School of Chemistry & Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

Corresponding author: Qian Xuefeng, mhshu@sjtu.edu.cn
Received Date: 12 September 2017
Revised Date: 10 November 2017
Available Online: 17 March 2017
Fund Project: the National Natural Science Foundation of China 21271129Project supported by the National Natural Science Foundation of China (No. 21271129)

Figures(6)

A porous organic polymer (POP) with chiral 2, 2'-bis(diphenylphosphino)-1, 1'-binaphthalene (BINAP) has been prepared and characterized by several techniques including ¹³C CP/MAS NMR, ³¹P CP/MAS NMR, fourier transform infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, transmission electron microscopy and nitrogen adsorption. The material exhibits amorphous microporous structure. After loading of ruthenium(Ⅱ) species via coordination, the composite material Ru/POP-BINAP could be used as a heterogeneous catalyst for the asymmetric hydrogenation of β-keto esters with high activity, excellent enantioselectivity and recyclability.
- porous organic polymer,
- heterogeneous catalysis,
- asymmetric hydrogenation,
- β-keto esters
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