Citation: Kong Shengnan, Abaid Ullah Malik, Qian Xuefeng, Shu Mouhai, Xiao Wende. C-C Coupling Reactions in Water Catalyzed by Palladium[J]. Chinese Journal of Organic Chemistry, ;2018, 38(2): 432-442. doi: 10.6023/cjoc201709016 shu

C-C Coupling Reactions in Water Catalyzed by Palladium

School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240

Corresponding author: Shu Mouhai, mhshu@sjtu.edu.cn
Received Date: 9 September 2017
Revised Date: 18 October 2017
Available Online: 3 March 2017
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21271129)the National Natural Science Foundation of China 21271129

Figures(6)

A microporous organic polymer bearing 2, 2'-bipyridine functional group (MOP-bipy), has been synthesized. After treating with Pd (CH₃CN)₂Cl₂, a composite material Pd/MOP-bipy was obtained. The materials have been characterized by ¹³C CP/MAS NMR, FT-IR, PXRD, SEM, TEM, nitrogen adsorption and thermogravimetric (TG) techniques. The content and valence of palladium in Pd/MOP-bipy have been determined by ICP and XPS. The composite material Pd/MOP-bipy exhibits excellent catalytic activity for Suzuki-Miyaura reaction in water and Sonogashira coupling reaction in methanol/water. The catalyst can be recycled at least five times without significant loss of the activity.
- microporous organic polymer,
- heterogeneous catalysis,
- palladium,
- Suzuki-Miyaura coupling,
- Sonogashira coupling
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