Citation: Tian Yajuan, Cai Ning, Chen Yatong, Qian Sainan, Huo Yanping. Dye-Sensitized Solar Cells: Progress on Robust Anchor Groups in Dyes[J]. Chinese Journal of Organic Chemistry, ;2018, 38(5): 1085-1106. doi: 10.6023/cjoc201709014 shu

Dye-Sensitized Solar Cells: Progress on Robust Anchor Groups in Dyes

Tian Yajuan ^a ,
Cai Ning ^a,, ,
Chen Yatong ^a ,
Qian Sainan ^a ,
Huo Yanping ^a,b,,

a.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006
b.
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Cheimstry, Chinese Academy of Sciences, Shanghai 200032

Corresponding author: Cai Ning, ning.cai@gdut.edu.cn Huo Yanping, organicteacherhuo@126.com
Received Date: 8 September 2017
Revised Date: 16 November 2017
Available Online: 8 May 2017
Fund Project: Project supported by the Natural Science Foundation of Guangdong Province (No. 2017A030310039), the National Natural Science Foundation of China (Nos. 61671162, 21372051) and the Science and Technology Planning Project of Guangdong Province (No. 2016A010103031)the National Natural Science Foundation of China 21372051the National Natural Science Foundation of China 61671162the Natural Science Foundation of Guangdong Province 2017A030310039the Science and Technology Planning Project of Guangdong Province 2016A010103031

Figures(2)

As a type of potential photovoltaic device, dye-sensitized solar cells (DSSCs) have attracted tremendous attention due to its high cost-effective and simple manufacturing process. In the device, dye molecules attach on the metal oxide surface via chemical bonds between anchor substituents and metal oxide substrate, realizing the light harvesting and photoelectron injection. Traditionally, carboxylic acids, such as benzoic acid and cyanoacrylic acid groups, have been widely utilized as the anchor groups in DSSCs. However, the detachment of dye molecules from metal oxide surface during device operation and consequent long-term stability issues cannot be ignored. Therefore, in view of durability of DSSCs in practical application, various anchor groups with a better ability to graft on the metal oxide have been explored. Several robust anchor groups in recent years and corresponding photovoltaic parameters are reviewed and the relationship between molecular structures and device performance is also discussed. The research progress of anchoring groups in photocatalytic hydrogen and quantum dot sensitized solar cells (QDSSCs) is also examined.
- dye-sensitized solar cell,
- dye sensitizer,
- anchor group,
- stability
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沈阳化工大学材料科学与工程学院沈阳 110142