Citation: Miao Siwen, Na Yong. Oxygenation of Organic Substrates Based on Light-Driven Water Oxidation[J]. Chinese Journal of Organic Chemistry, ;2018, 38(3): 575-584. doi: 10.6023/cjoc201709006 shu

Oxygenation of Organic Substrates Based on Light-Driven Water Oxidation

Miao Siwen ,
Na Yong ^,

Department of Applied Chemistry, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001

Corresponding author: Na Yong, yongna@hit.edu.cn
Received Date: 5 September 2017
Revised Date: 12 October 2017
Available Online: 3 March 2017
Fund Project: Project supported by the National Natural Science Foundation of China (No. 21603046)the National Natural Science Foundation of China 21603046

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Hydrogen production by artificial photosynthetic water splitting is an efficient approach to convert solar ennergy into chemical bonds. Oxygenation of an organic substrate based on light-driven water oxidation is innovative way to mimic the oxygen evolving center (OEC) in Photosystem Ⅱ. The metal catalyst will accomplish H₂O activation to generate high valent metal-oxo intermediate, which can transfer the oxygen atom to an organic substrate, during which the H atoms in H₂O molecule could be released. This review is a perspective of the recent advances in oxygenation of organic substrates with water as oxygen source. In the meanwhile, research prospect on photocatalytic hydrogen production coupled with the photocatalytic oxygenation of an organic substrate for a new water splitting system has been proposed.
- artificial photosynthesis,
- water molecule activation,
- metal-oxo intermediate,
- oxygenation of organic substrates
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