Citation: Li Yabo, Shen Zhen, Huang Mengmeng, Zhang Jianye, Kim Jung Keun, Wu Yangjie. Highly Catalytic Activity of Bis(alkoxo)palladium Complexes for Fujiwara-Moritani Reaction[J]. Chinese Journal of Organic Chemistry, ;2018, 38(1): 200-207. doi: 10.6023/cjoc201708063 shu

Highly Catalytic Activity of Bis(alkoxo)palladium Complexes for Fujiwara-Moritani Reaction

College of Chemistry and Molecular Engineering, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052

Corresponding author: Huang Mengmeng, hmm@zzu.edu.cn Kim Jung Keun, kim@zzu.edu.cn
Received Date: 30 August 2017
Revised Date: 19 September 2017
Available Online: 26 January 2017
Fund Project: National Natural Science Foundation of China 21172200National Natural Science Foundation of China 21302172Project supported by the National Natural Science Foundation of China (Nos. 21172200, 21302172)

Figures(3)

A series of bis(alkoxo)palladium complexes (2 mol%) based on pyridine-containing alcohol ligand were tested for Fujiwara-Moritani reaction of thiophenes/furans with various olefins. The desired products were isolated in moderate to excellent yields under mild conditions. A possible concerted metalation-deprotonation (CMD) pathway for this transformation was proved by control experiments and ESI(+)-MS analysis.
- bis(alkoxo)palladium complex,
- Fujiwara-Moritani reaction,
- CMD pathway,
- pyridine-containing alcohol ligand
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