Citation: Yang Qi, Liu Liang, Zhang Wen-Xiong, Xi Zhenfeng. Gold(Ⅰ)-Catalyzed 1, 2-Migration of a SiMe₃ Group on Naphthalene Rings[J]. Chinese Journal of Organic Chemistry, ;2018, 38(1): 272-276. doi: 10.6023/cjoc201708059 shu

Gold(Ⅰ)-Catalyzed 1, 2-Migration of a SiMe₃ Group on Naphthalene Rings

College of Chemistry, Peking University, Beijing 100871

Corresponding author: Xi Zhenfeng, zfxi@pku.edu.cn
Received Date: 29 August 2017
Revised Date: 19 September 2017
Available Online: 19 January 2017
Fund Project: the National Natural Science Foundation of China 21690061Project supported by the National Natural Science Foundation of China (Nos. 21372012, 21690061)the National Natural Science Foundation of China 21372012

Figures(3)

A gold(Ⅰ)-catalyzed 1, 2-silyl migration on 1, 8-di-substituted naphthalene rings was realized by synergistic effect of Lewis acid and water. High yields were achieved under relatively mild conditions.
- gold(Ⅰ)-catalysis,
- 1, 2-silyl migration,
- 1, 8-di-substituted naphthalene ring,
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Gold(Ⅰ)-Catalyzed 1, 2-Migration of a SiMe3 Group on Naphthalene Rings

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Gold(Ⅰ)-Catalyzed 1, 2-Migration of a SiMe₃ Group on Naphthalene Rings